Hi JimL65, dsags & Jim. On a 65 Skylark,Special without AC. The heater core is very simple. At 58 years old most of these Buicks don't have there original core which means that 5th nut that is under the inner well has already been removed and discarded by other mechanics. So just remove the 4 nuts and the cables on the inside. And make a note or take a photo of the color coded cables and where they attach. Then see if the the box can be pulled back and out. if not then follow the instructions that dsags posted to remove the 5th nut.
On all the "A" body buicks that I have owned I have only encountered the 5th nut once and that's on my current 65 post coupe project because the Buick was sent to the scrapyard in 1970 and the second owner that rescued it from the yard (Steve Shuman) never replaced the core. I'm the 3rd owner.
As far as the 2 bolts that you mentioned, I'm looking at the Chassis service manual and the GM parts catalog #674A group 9.000 Illustration #9 and I don't see 2 bolts. the 2 bolts may be for an AC "A" body. If you have an AC "A" body I'm sure some of the other member can assist you.
If you want copies of the Illustrations that I have just send me a PM with your info and I will send them out to you.
Tony...