The later EGR systems were the ones that brought exhaust gas back into the intake tract. Early 1970's. It's purpose is to lower combustion temperatures to reduce N2O emissions.
The PCV will recycle most crankcase gasses (blow by) back into the intake. Suppose those gasses could be considered to be comprised of 'exhaust'. The open PCV (with open breather) will vent any excess blowby to atmosphere, whereas the closed PCV will try to capture the excess and route it to the air cleaner.
For 1966, they added the smog pump which will use some engine power to drive. It injects air into the exhaust to allow unburnt fuel to continue burning.
Bob, the 4 bbl '66 Carbs with Calif smog systems did have smaller primary venturi's......I'll guess that reduces the cfm, and horsepower.
As for the GS AC compressor, I have one from a '66 Riv GS and the label, IIRC, Says it's for the GS's.